A Nano-Solution to Global Water Problem: Nanomembranes Could Filter Bacteria
Apr 12, 2011
New nanomaterials research from the University at Buffalo could lead to new solutions for an age-old public health problem: how to separate bacteria from drinking water.
To the naked eye, both water molecules and germs are invisible -- objects so tiny they are measured by the nanometer, a unit of length about 100,000 times thinner than the width of a human hair.
But at the microscopic level, the two actually differ greatly in size. A single water molecule is less than a nanometer wide, while some of the most diminutive bacteria are a couple hundred.
Working with a special kind of polymer called a block copolymer, a UB research team has synthesized a new kind of nanomembrane containing pores about 55 nanometers in diameter -- large enough for water to slip through easily, but too small for bacteria.
The pore size is the largest anyone has achieved to date using block copolymers, which possess special properties that ensure pores will be evenly spaced, said Javid Rzayev, the UB chemist who led the study. The findings were published online on Jan. 31 in Nano Letters and will appear in the journal's print edition later this year, with UB chemistry graduate student Justin Bolton as lead author.
"These materials present new opportunities for use as filtration membranes," said Rzayev, an assistant professor of chemistry. "Commercial membranes have limitations as far as pore density or uniformity of the pore size. The membranes prepared from block copolymers have a very dense distribution of pores, and the pores are uniform."
"There's a lot of research in this area, but what our research team was able to accomplish is to expand the range of available pores to 50 nanometers in diameter, which was previously unattainable by block-copolymer-based methods," Rzayev continued. "Making pores bigger increases the flow of water, which will translate into cost and time savings. At the same time, 50 to 100 nm diameter pores are small enough not to allow any bacteria through. So, that is a sweet spot for this kind of application."
The new nanomembrane owes its special qualities to the polymers that scientists used to create it. Block copolymers are made up of two polymers that repel one another but are "stitched" together at one end to form the single copolymer.
When many block copolymers are mixed together, their mutual repulsion leads them to assemble in a regular, alternating pattern. The result of that process, called self-assembly, is a solid nanomembrane comprising two different kinds of polymers.
To create evenly spaced pores in the material, Rzayev and colleagues simply removed one of the polymers. The pores' relatively large size was due to the unique architecture of the original block copolymers, which were made from bottle-brush molecules that resemble round hair brushes, with molecular "bristles" protruding all the way around a molecular backbone.
The research on nanomembranes is part of a larger suite of studies Rzayev is conducting on bottle-brush molecules using a National Science Foundation CAREER award, the foundation's most prestigious award for junior investigators. His other work includes the fabrication of organic nanotubes for drug delivery, and the assembly of layered, bottle-brush polymers that reflect visible light like the wings of a butterfly do.
The University at Buffalo is a premier research-intensive public university, a flagship institution in the State University of New York system and its largest and most comprehensive campus. UB's more than 28,000 students pursue their academic interests through more than 300 undergraduate, graduate and professional degree programs. Founded in 1846, the University at Buffalo is a member of the Association of American Universities.
More News and Articles
Aug 28, 2024
News
ITpipes Secures $20M to Transform Water Infrastructure Management
ITpipes announced it has secured $20 million in equity financing from Trilogy Search Partners and Miramar Equity Partners.
Known for its trusted and user-friendly platform, ITpipes …
Aug 26, 2024
News
Professor Dr.-Ing. Dietrich Stein
With deep sadness we announce the loss of our founder and partner Prof Dr Dietrich Stein at the age of 85.
Engineers around the globe are thankful for his dedication to the inventions in the fields of sewers, …
Aug 26, 2024
News
PPI Releases New Installation Guide for PE4710 Pipe
PPI’s MAB-11-2024 Covers HDPE Water Pipelines Up to 60-in. Diameter and 10,000-ft Long Pulls
Developed by the Municipal Advisory Board (MAB) – and published with the help of the members of the …
Aug 23, 2024
News
Faster wide-scale leak detection now within reach
Mass deployment of connected leak loggers is being made possible by the latest technology, writes Tony Gwynne, global leakage solutions director, Ovarro
Water companies in England and Wales are …
Aug 21, 2024
News
Kraken awakens customer service potential in water
The innovative customer service platform Kraken has made a successful transfer from energy to water. Ahead of their presentation at UKWIR’s annual conference, Portsmouth Water chief executive …
Aug 19, 2024
News
Predicting the toxicity of chemicals with AI
Researchers at Eawag and the Swiss Data Science Center have trained AI algorithms with a comprehensive ecotoxicological dataset. Now their machine learning models can predict how toxic chemicals are …
Aug 16, 2024
News
Goodbye water loss: Trenchless pipe renewal in Brazil
Pipe renewal in Brazil
How do you stop water loss through leaks in old pipe systems without major environmental impacts and restrictions? The answer: with trenchless technology, or more precisely …
Aug 14, 2024
Article
Impact of high-temperature heat storage on groundwater
In a recently launched project, the aquatic research institute Eawag is investigating how the use of borehole thermal energy storage (BTES) affects the surrounding soil, the groundwater …
Aug 12, 2024
News
Watercare completes East Coast Bays sewer link
Watercare has successfully finished the final connection on the East Coast Bays link sewer at Windsor Park in New Zealand.
Much of the East Coast Bays sewer link was installed using horizontal directional …
Aug 09, 2024
Article
Innovative water solutions for sustainable cities
Cities need to become more sustainable and use their water resources more efficiently. Managing water in local small-scale cycles is one possible solution. A new white paper by Eawag, the University …
Aug 07, 2024
Article
How digital technologies contribute to universal drinking water
Digital water technologies have an important role in ensuring universal access to safe drinking water by 2030, that is according to a new report from the World Health Organisation. …
Aug 05, 2024
News
Knowledge transfer on sustainable water infrastructure in India
India’s fast-growing cities need an efficient infrastructure for water supply and wastewater disposal. A research cooperation, is therefore supporting the development of a sustainable …